Z-D-PIPECOLIC ACID
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic
CAS: 28697-11-2
Molecular Formula: C14H17NO4
Z-D-PIPECOLIC ACID - Names and Identifiers
| Name | (S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic |
| Synonyms | Z-D-PIP-OH Z-D-PIPECOLIC ACID Z-D-PIPECOLINIC ACID (L)-N-CBZ-PIPECOLIC ACID N-Cbz-L-pipecolinic acid (-)-N-CBZ-L-PIPECOLINIC ACID (S)-1-N-Cbz-Pipecolinic acid (L)-N-(Benzyloxycarbonyl)Pipecolic Acid (L)-N-(BENZYLOXYCARBONYL)PIPECOLIC ACID N-BENZYLOXYCARBONYL-(S)-(-)-PIPECOLINIC ACID PIPERIDINE-1,2-DICARBOXYLIC ACID 1-BENZYL ESTER (S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic (S)-()-1-(Carbobenzyloxy)-2-piperidinecarboxylic acid (2S)-1-[(benzyloxy)carbonyl]piperidine-2-carboxylic acid |
| CAS | 28697-11-2 |
| InChI | InChI=1/C14H17NO4/c16-13(17)12-8-4-5-9-15(12)14(18)19-10-11-6-2-1-3-7-11/h1-3,6-7,12H,4-5,8-10H2,(H,16,17)/t12-/m0/s1 |
Z-D-PIPECOLIC ACID - Physico-chemical Properties
| Molecular Formula | C14H17NO4 |
| Molar Mass | 263.29 |
| Density | 1.265 |
| Melting Point | 111-115°C(lit.) |
| Boling Point | 443.9°C at 760 mmHg |
| Flash Point | 222.3°C |
| Vapor Presure | 1.16E-08mmHg at 25°C |
| Storage Condition | 2-8°C |
| Refractive Index | 1.568 |
| MDL | MFCD01863645 |
Z-D-PIPECOLIC ACID - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | R36/37/38 - Irritating to eyes, respiratory system and skin. R38 - Irritating to the skin R37 - Irritating to the respiratory system R36 - Irritating to the eyes |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. |
| WGK Germany | 3 |
Z-D-PIPECOLIC ACID - Introduction
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic ((S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic) is an organic compound, its molecular formula is C19H21NO4.
Nature:
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-boxylic is a white to pink solid that is relatively stable at room temperature. It has a fixed melting point and boiling point and can be dissolved in many organic solvents.
Use:
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic is widely used as a protecting group in organic synthesis and can be used to protect amine groups. It can selectively protect amine groups in organic synthesis reactions to prevent unwanted chemical reactions of other functional groups.
Method:
The preparation method of (S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic can be obtained by combining piperidinecarboxylic acid with chloromethyl benzoate (Cbz-Cl) in the presence of a base Reaction, the desired product was generated. This method requires attention to the choice of reaction conditions and solvents to ensure high yield and purity.
Safety Information:
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic may be toxic to humans, so appropriate safety measures must be taken when handling and using. It should be kept away from fire and high temperature, and avoid contact with oxidants and acids. Appropriate protective equipment such as gloves, goggles and protective clothing should be worn during operation. Maintain a well-ventilated laboratory environment and properly store and handle chemicals. In the course of use, should follow the relevant safety procedures and guidelines for the use of chemicals.
Nature:
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-boxylic is a white to pink solid that is relatively stable at room temperature. It has a fixed melting point and boiling point and can be dissolved in many organic solvents.
Use:
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic is widely used as a protecting group in organic synthesis and can be used to protect amine groups. It can selectively protect amine groups in organic synthesis reactions to prevent unwanted chemical reactions of other functional groups.
Method:
The preparation method of (S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic can be obtained by combining piperidinecarboxylic acid with chloromethyl benzoate (Cbz-Cl) in the presence of a base Reaction, the desired product was generated. This method requires attention to the choice of reaction conditions and solvents to ensure high yield and purity.
Safety Information:
(S)-(-)-1-(carbobenzyloxy)-2-piperidine-carboxylic may be toxic to humans, so appropriate safety measures must be taken when handling and using. It should be kept away from fire and high temperature, and avoid contact with oxidants and acids. Appropriate protective equipment such as gloves, goggles and protective clothing should be worn during operation. Maintain a well-ventilated laboratory environment and properly store and handle chemicals. In the course of use, should follow the relevant safety procedures and guidelines for the use of chemicals.
Last Update：2024-04-10 22:29:15
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View History
Z-D-PIPECOLIC ACID
Cinnamic acid, p-hydroxy-, methyl ester (8CI)
3-CHLOROPROPIONYL CHLORIDE FOR SYNTHESIS
PROLANT
CARBAMOYLGUANIDINE PHOSPHATE
C.I.Acid Brown 349
2-chloro-propionicacimethylester
Acid brown 52
Cinnamic acid, p-hydroxy-, methyl ester (8CI)
3-CHLOROPROPIONYL CHLORIDE FOR SYNTHESIS
PROLANT
CARBAMOYLGUANIDINE PHOSPHATE
C.I.Acid Brown 349
2-chloro-propionicacimethylester
Acid brown 52